People have been coloring with natural dyes – animal, vegetable or mineral – since prehistoric times. Dyeing wool fleece or yarn (animal or protein fibers~ vs~ vegetable/plant fibers) with dyes you create from plants, bark, roots, insects, food and such is a rewarding colorful adventure!

Photo courtesty The Natural Knitter by B. Albright; wool fleece dyed with (top clockwise) brazilwood,logwood,mullein & goldenrod.
Categories of Natural Dyes:
1. Substantive Dyes – dyes fixed within the fibers without assistance of other substances or mordants
2. Adjective Dyes – require a mordant for color development and permanently “fix” to fiber
3. Vat Dyes – substantive dyes, but insoluble in water; deposited on external surface of fiber; color develops upon exposure to oxygen (indigo, woad = blue) or light (shellfish + purple)
Mordants Matter!
French mordre, ‘to bite’; boiled with the fiber to chemically fix the dye to the fiber; often produces much stronger color on fibers. Mordants join the fiber with the dye to set the color permanently. The most common mordants are:
– Alum – common pre-mordant; use with cream of tartar (too much can make wool sticky!); 8% alum or 1- ¾ tsp per 4 oz (100 g) fiber + 7% cream of tartar or 1- ½ tsp per 4 oz (100 g) fiber
– Copper – gives similar results as chrome, but slightly more green; to make copper liquor, add several pieces of copper pipe to a 1:1 solution of water & distilled vinegar to a glass jar
– Iron – ‘saddens’ or dulls (too much can weaken fiber); to make iron liquor, add rusty nails to a 2:1 solution of water & distilled vinegar
– Chrome – toxic; rich, deep color; more permanent than alum; leaves wool feeling soft, silky
– Tin – enhances and brightens
– Oxalic acid – toxic (found naturally in rhubarb leaves – caution toxic!). To make mordant from rhubarb leaves, simmer 1 pound rhubarb leaves in water w/covered pot outdoors or in a well-ventilated work area for 1 hr; strain.
Assistants
– Cream of Tartar – used with Al mordants
– Vinegar (5 % distilled) – used with Cu; increase acidity
– Ammonia – used with Al & indigo; increase alkalinity
Variables affecting the natural plant dye bath (in terms of RELIABILITY, PREDICTABILITY and CONSISTENT Dye Results):
– Moisture and temperature during the plant growing season
– Plant’s stage of growth when harvested for dyestuff
– What part of plant was gathered
– Used immediately or stored (fresh vs. dried)
– How long was dye bath simmered or soaked
– Water pH & mineral content (municipal water, well water, bottled water?)
– Bath temperature during dyeing
– Ratio of weight of dye plant to weight of fiber (WOF)
– Mordant used (pre or post treatment)
3 Basic Methods of Dyeing:
♣ Mordant wool first, then add it to the dye bath
♣ Mordant and dye wool in the same dye-bath
♣ Dye wool first, then FIX by mordanting
Simply put, Basic Steps for Dyeing Wool (Protein) Fibers:
1. Pre-Treatment – scouring, weighing, mordanting (alum is most common)
2. Making a dye bath; extracting the dye (substantive dyes or adjective dyes = mordant-assisted)
3. Dyeing the fiber
4. Post-mordanting
5. Rinsing
6. Air drying
Finally, in DYEING PART III, we’ll talk about preparing a dye bath, dyeing, recordkeeping, simple recipes to get started & resources!
Blessings!
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